不同化学成分的耐火材料,在相互作用下的反应温度
高温下,耐火材料不同化学成分之间可能产生不良反应,是不可以的,例如镁质砌体存在一系列硅酸铝制品成分。实验室研究结果,见表10-3,列举了各种耐火材料之间发生反应的温度。不同化学成分制品之间必须砌上中性耐火材料衬垫物,常常是铬质的。
表10-3 各种耐火材料相互作用的反应温度(℃) |
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耐火材料 |
硅砖 |
黏土砖 |
高铝制品 Al2O3;70% |
铬质制品 |
镁橄榄石质制品 |
铬镁质制品 |
镁铬质制品 |
镁质制品 |
硅砖 |
– |
1500 — 1600 |
1000 |
1650 |
1700 |
1600 |
1600 |
1500 |
黏土砖 |
1500 —— 1600 |
– |
– |
1600 — 1600 |
1500 — 1600 |
1600 — 1650 |
1600 — 1650 |
1400 — 1500 |
高铝制品 Al2O70% |
1600 |
– |
– |
1600 —1600 |
16501700 |
1600 — 1700 |
1600 — 1700 |
1500 — 1600 |
铬质制品 |
1650 |
1600 |
1600 —1600 |
1600 |
1700 |
1700 |
1700 |
|
镁橄榄石质 |
1700 |
1500 — 1600 |
1650 — 1700 |
16001650 |
– |
1700 |
1700 |
1700 ——1700 |
铬镁制品 |
1600 |
1600 |
1600 — 1700 |
1700 |
– |
– |
– |
– |
镁铬制品 |
1600 — 1700 |
1600 — 1650 |
1600 — 1700 |
1700 |
1700 |
– |
– |
– |
镁质制品 |
1500 — 1600 |
1400 — 1600 |
1500 — 1700 |
1700 |
1700 — 1700 |
– |
– |
– |
注:分子为开始反应温度;分母为开始引起破坏的反应温度。 |
Reaction temperature of refractories with different chemical composition under interaction
At high temperatures, adverse reactions may occur between different chemical components of refractory materials, which is not possible, such as magnesium masonry with a series of aluminum silicate product components. Laboratory research results, shown in Table 10-3, list the temperatures at which reactions occur between various refractories. A neutral refractory liner, often chrome, must be lined between products of different chemical compositions.
Table 10-3 Reaction temperature of various refractories interaction (℃) |
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Refractory |
Silica brick |
Clay brick |
High aluminum product Al2O3;70% |
Chrome product |
Magnesium olivine products |
Chrome magnesium products |
Magnesium chrome products |
Magnesium product |
Silica brick |
– |
1500 — 1600 |
1000 |
1650 |
1700 |
1600 |
1600 |
1500 |
Clay brick |
1500 — 1600 |
– |
– |
1600 — 1600 |
1500 — 1600 |
1600 — 1650 |
1600 — 1650 |
1400 — 1500 |
High aluminum productAl2O370% |
1600 |
– |
– |
1600 — 1600 |
16501700 |
1600 — 1700 |
1600 — 1700 |
1500 — 1600 |
Chrome product |
1650 |
1600 |
1600 — 1600 |
1600 |
1700 |
1700 |
1700 |
|
Magnesium olivine product |
1700 |
1500 — 1600 |
1650 — 1700 |
16001650 |
– |
1700 |
1700 |
1700 — 1700 |
Chrome-magnesium products |
1600 |
1600 |
1600 — 1700 |
1700 |
– |
– |
– |
– |
Magnesium-chromium products |
1600 —1700 |
1600 — 1650 |
1600 — 1700 |
1700 |
1700 |
– |
– |
– |
Magnesium product |
1500 —1600 |
1400 —1600 |
1500 — 1700 |
1700 |
1700 — 1700 |
– |
– |
– |
Note: The molecule is the initial reaction temperature; The denominator is the reaction temperature at which the damage begins. |